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Dr. Vincent's Publication List: 1986-1998

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1. "Model complexes suggest certain S-state changes of the photosynthetic water-oxidation enzyme may involve a manganese(II)-manganese(III) transition." Vincent, J. B.; Christou, G. FEBS Lett. 207, 250-2 (1986).

2. "Use of tetra-n-butylammonium permanganate for inorganic syntheses in nonaqueous solvents. Preparation and structure of a manganese(III) dimer containing bridging phenoxo oxygen atoms." Vincent, J. B.; Folting, K.; Huffman, J. C.; Christou, G. Inorg. Chem. 25, 996-9 (1986).

3. "Support from model studies for the proposed existence of and S-1 oxidation level in the manganese assembly of the photosynthetic water oxidation center." Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H. R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun., 1303-5 (1987).

4. "Salicylate-facilitated compounds of distinct mixed-valence nonanuclear manganese complexes, [Mn9O4(O2CPh)8(sal)4(salH)2(py)4] (salH2 = salicylic acid, py = pyridine)." Christmas, C.; Vincent, J. B.; Huffman, J. C.; Christou, G.; Chang, H. R.; Hendrickson, D. N. Angew. Chem. 99, 934-6 (1987).

5. "The molecular 'double-pivot' mechanism for water oxidation." Christou, G.; Vincent, J. B. Biochim. Biophys. Acta, Rev. Bioenerg. 895, 259-74 (1987).

6. "Preparation and physical properties of trinuclear oxo-centered manganese complexes of general formulation [Mn3O(O2CR)6L3]0,+ (R = methyl or phenyl; L = a neutral donor group) and the crystal structures of [Mn3O(O2CMe)6(pyr)3](pyr) and [Mn3O(O2CPh)6(pyr)2(H2O)]·0.5MeCN." Vincent, J. B.; Chang, H. R.; Folting, K.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 109, 5703-11 (1987).

7. "Modeling the photosynthetic water oxidation center: synthesis, structure, and magnetic properties of [Mn4O2(OAc)7(bipy)2](ClO4)·3H2O (bipy = 2,2'-bipyridine)." Vincent, J. B.; Christmas, C.; Huffman, J. C.; Christou, G.; Chang, H. R.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun., 236-8 (1987).

8. "A molecular double-pivot mechanism for water oxidation." Vincent, J. B.; Christou, G. Inorg. Chim. Acta 136, L41-L43 (1987).

9. "Mixed valence manganese(II, III) and -(III, IV) dinuclear complexes. Preparation, structure, magnetochemistry, and ESR spectra of Mn2(biphen)2(biphenH)(bpy)2 and Mn2O2Cl2(OAc)(bpy)2 (biphenH2 = 2,2'-biphenol, bpy = 2,2'-bipyridine)." Bashkin, J. S.; Schake, A. R.; Vincent, J. B.; Chang, H. R.; Li, Q.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Chem. Soc., Chem. Commun., 700-2 (1988).

10. "Potential building blocks for molecular ferromagnets: [Mn12O12(O2CPh)16(H2O)4] with a S = 14 ground state." Boyd, P. D. W.; Li, Q.; Vincent, J. B.; Folting, K.; Chang, H. R.; Streib, W. E.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 110, 8537-9 (1988).

11. "Nonanuclear oxide-bridged manganese complex. Preparation, structure, and magnetic properties of [Mn9O4(O2CPh)8(sal)4(salH)2(pyr)4] (salH2 = salicylic acid; pyr = pyridine)." Christmas, C.; Vincent, J. B.; Chang, H. R.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 110, 823-30 (1988).

12. "Structural types in oxide-bridged manganese chemistry: toward a model of the photosynthetic water oxidation center." Christou, G.; Vincent, J. B. ACS Symposium Series 372, 238-55 (1988).

13. "Carbon-hydrogen activation chemistry: hydroxylation of C2, C3, and cyclo-C6 hydrocarbons by manganese cluster catalysts with a monooxygen transfer reagent." Fish, R. H.; Fong, R. H.; Vincent, J. B.; Christou, G. J. Chem. Soc., Chem. Commun., 1504-6 (1988).

14. "Structure, magnetochemistry, and biological activity of [Mn4O3Cl4(OAc)3(Py)3], a complex with S = 9/2 ground state." Li, Q.; Vincent, J. B.; Libby, E.; Chang, H. R.; Huffman, J. C.; Boyd, P. D. W.; Christou, G.; Hendrickson, D. N. Angew. Chem. 100, 1799-801 (1988).

15. "Dinuclear manganese-oxide complexes as models for manganese catalase." Vincent, J. B.; Folting, K.; Huffman, J. C.; Christou, G. Biochem. Soc. Trans. 16, 822-3 (1988).

16. "Modeling the dinuclear sites of iron biomolecules: synthesis and properties of Fe2O(OAc)2Cl2(bipy)2 and its use as an alkane activation catalyst." Vincent, J. B.; Huffman, J. C.; Christou, G.; Li, Q.; Nanny, M. A.; Hendrickson, D. N.; Fong, R. H.; Fish, R. H. J. Am. Chem. Soc. 110, 6898-900 (1988).

17. "Hydroxylation of C2, C3, and cyclo-C6 hydrocarbons by manganese porphyrin and nonporphyrin catalysts." Fish, R. H.; Fong, R. H.; Price, R. T.; Vincent, J. B.; Christou, G. ACS Symposium Series 392, 116-22 (1989).

18. "Highly cooperative valence detrapping of mixed-valence manganese complex [Mn3O(O2CCH3)6(py)3](py) in the solid state." Jang, H. G.; Vincent, J. B.; Nakano, M.; Huffman, J. C.; Christou, G.; Sorai, M.; Wittebort, R. J.; Hendrickson, D. N. J. Am. Chem. Soc. 111, 7778-84 (1989).

19. "Heat capacity study of the abrupt valence-detrapping phase transition of mixed-valence hexakis(acetato)oxotris(pyridine)trimanganese.pyridine." Nakano, M.; Sorai, M.; Vincent, J. B.; Christou, G.; Jang, H. G.; Hendrickson, D. N. Inorg. Chem. 28, 4608-14 (1989).

20. "Preparation, structure, and magnetochemistry of hexanuclear manganese oxide complexes: chemically and thermally induced aggregation of aquahexakis(benzoato)oxobis(pyridine)trimanganese forming products containing the [Mn6O2]10+ core." Schake, A. R.; Vincent, J. B.; Li, Q.; Boyd, P. D. W.; Folting, K.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. Inorg. Chem. 28, 1915-23 (1989).

21. "Modeling the photosynthetic water oxidation center. Preparation and properties of tetranuclear manganese complexes containing [Mn4O2]6+,7+,8+ cores, and the crystal structures of Mn4O2(O2CMe)6(bipy)2 and [Mn4O2(O2CMe)7(bipy)2](ClO4)." Vincent, J. B.; Christmas, C.; Chang, H. R.; Li, Q.; Boyd, P. D. W.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 111, 2086-97 (1989).

22. "Higher oxidation state manganese biomolecules." Vincent, J. B.; Christou, G. Adv. Inorg. Chem. 33, 197-257 (1989).

23. "An enzyme with a double identity: purple acid phosphatase and tartrate-resistant acid phosphatase." Vincent, J. B.; Averill, B. A. FASEB J. 4, 3009-14 (1990).

24. "Sequence homology between purple acid phosphatases and phosphoprotein phosphatases: are phosphoprotein phosphatases metalloproteins containing oxide-bridged dinuclear metal centers?" Vincent, J. B.; Averill, B. A. FEBS Lett. 263, 265-8 (1990).

25. "Proteins containing oxo-bridged dinuclear iron centers: a bioinorganic perspective." Vincent, J. B.; Olivier-Lilley, G. L.; Averill, B. A. Chem. Rev. 90, 1447-67 (1990).

26. "Biomimetic oxidation studies. 5. Mechanistic aspects of alkane functionalization with iron and iron-oxygen (Fe2O and Fe4O2) complexes in the presence of hydrogen peroxide." Fish, R. H.; Konings, M. S.; Oberhausen, K. J.; Fong, R. H.; Yu, W. M.; Christou, G.; Vincent, J. B.; Coggin, D. K.; Buchanan, R. M. Inorg. Chem. 30, 3002-6 (1991).

27. "Molecular spin frustration in the [Fe4O2]8+ core: synthesis, structure, and magnetochemistry of tetranuclear iron-oxo complex [Fe4O2(O2CR)7(bpy)2](C1O4) (R = Me, Ph)." McCusker, J. K.; Vincent, J. B.; Schmitt, E. A.; Mino, M. L.; Shin, K.; Coggin, D. K.; Hagen, P. M.; Huffman, J. C.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 113, 3012-21 (1991).

28. "Evidence for a phosphoryl-enzyme intermediate in phosphate ester hydrolysis by purple acid phosphatase from bovine spleen." Vincent, J. B.; Crowder, M. W.; Averill, B. A. J. Biol. Chem. 266, 17737-40 (1991).

29. "Spectroscopic and kinetics studies of a high-salt-stabilized form of the purple acid phosphatase from bovine spleen." Vincent, J. B.; Crowder, M. W.; Averill, B. A. Biochemistry 30, 3025-34 (1991).

30. "Electron paramagnetic resonance studies on the high-salt form of bovine spleen purple acid phosphatase." Crowder, M. W.; Vincent, J. B.; Averill, B. A. Biochemistry 31, 9603-8 (1992).

31. "Biomimetic oxidation studies. 6: Synthetic and mechanistic aspects of manganese cluster mediated alkane functionalization reactions." Fish, R. H.; Fong, R. H.; Oberhausen, K. J.; Konings, M. S.; Vega, M. C.; Christou, G.; Vincent, J. B.; Buchanan, R. M. New J. Chem. 16, 727-33 (1992).

32. "Photosynthetic water oxidation center: spin frustration in distorted cubane MnIVMnIII3 model complexes." Hendrickson, D. N.; Christou, G.; Schmitt, E. A.; Libby, E.; Bashkin, J. S.; Wang, S.; Tsai, H. L.; Vincent, J. B.; Boyd, P. D. W.; et al. J. Am. Chem. Soc. 114, 2455-71 (1992).

33. "Hydrolysis of phosphate monoesters: a biological problem with multiple chemical solutions." Vincent, J. B.; Crowder, M. W.; Averill, B. A. Trends. Biochem. Sci. 17, 105-10 (1992).

34. "Multiple binding sites for tetrahedral oxyanion inhibitors of bovine spleen purple acid phosphatase." Vincent, J. B.; Crowder, M. W.; Averill, B. A. Biochemistry 31, 3033-7 (1992).

35. "Proton NMR and NOE studies of the purple acid phosphatases from porcine uterus and bovine spleen." Wang, Z.; Ming, L. J.; Que, L., Jr.; Vincent, J. B.; Crowder, M. W.; Averill, B. A. Biochemistry 31, 5263-8 (1992).

36. "Electronic absorption spectroscopy of nonheme iron proteins." Averill, B. A.; Vincent, J. B. Meth. Enzymol. 226, 33-51 (1993).

37. "Nuclear magnetic resonance studies of multinuclear chromium assemblies." Glass, M. M.; Belmore, K.; Vincent, J. B. Polyhedron 12, 133-40 (1993).

38. "High-spin molecules: [Mn12O12(O2CR)16(H2O)4]." Sessoli, R.; Tsai, H. L.; Schake, A. R.; Wang, S.; Vincent, J. B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 115, 1804-16 (1993).

39. "Models of the manganese catalase enzymes. Dinuclear manganese(III) complexes with the [Mn2(μ-O)(μ-O2CR)2]2+ core and terminal monodentate ligands: preparation and properties of [Mn2O(O2CR)2X2(bpy)2] (X = chloride, azide, water)." Vincent, J. B.; Tsai, H. L.; Blackman, A. G.; Wang, S.; Boyd, P. D. W.; Folting, K.; Huffman, J. C.; Lobkovsky, E. B.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 115, 12353-61 (1993).

40. "Ultraviolet difference absorbance spectra of oxo-bridged manganese complexes: relationship to the photosynthetic Mn and Mn catalase." Wells, W.; Harton, A.; Vincent, J. B. Biochim. Biophys. Acta, Bioenerg. 1144, 346-52 (1993).

41. "Carbon-13 NMR studies of oxo-centered trinuclear chromium(III) complexes of the general formula [Cr3O(O2CR)6(L)3]+ (R = Me, Ph; L = H2O, py)." Belmore, K.; Madison, X. J.; Harton, A.; Vincent, J. B. Spectrochim. Acta, Part A 50A, 2365-70 (1994).

42. "Potential for decontamination of plutonium-containing solutions using Transferrin Metalloprotein Affinity Metal Chromatography." Donald, S.; Spires, K.; Vincent, J. B. J. Inorg. Biochem. 56, 167-71 (1994).

43. "Synthetic Models for Low-Molecular-Weight Chromium-Binding Substance: Synthesis and Characterization of Oxo-Bridged Tetranuclear Chromium(III) Assemblies." Ellis, T.; Glass, M.; Harton, A.; Folting, K.; Huffman, J. C.; Vincent, J. B. Inorg. Chem. 33, 5522-7 (1994).

44. "Synthesis and characterization of symmetric and unsymmetric oxo-bridged trinuclear chromium benzoate complexes: crystal and molecular structure of [Cr3O(O2CPh)6(py)3]ClO4." Harton, A.; Nagi, M. K.; Glass, M. M.; Junk, P. C.; Atwood, J. L.; Vincent, J. B. Inorg. Chim. Acta 217, 171-9 (1994).

45. "Heterotrinuclear Carboxylates of Chromium(III) and Iron(III): Mixtures or Pure Compounds?" Vincent, J. B. Inorg. Chem. 33, 5604-6 (1994).

46. "Relationship between glucose tolerance factor and low-molecular-weight chromium-binding substance. Comments." Vincent, J. B. J. Nutr. 124, 117-18 (1994).

47. "Metal ion concentration, time, and pH dependence of metal ion binding to a transferrin metalloprotein affinity chromatography (MAMC) matrix." Cannell, K. P.; Vincent, J. B. J. Chem. Techn. Biotechn. 64, 96-100 (1995).

48. "Modeling chromium biochemistry: synthesis and characterization of [NEt3H][CrIII4O2(O2CPh)7(pic)2]·CH2Cl2 (Hpic = picolinic acid)." Donald, S.; Terrell, K.; Vincent, J. B.; Robinson, K. D. Polyhedron 14, 971-6 (1995).

49. "Carbonic anhydrase and carboxypeptidase A metalloprotein affinity metal chromatography." Litaker, J.; Donald, S.; Spears, R.; Vincent, J. B. Min. Metallurg. Proc. 12, 108-11 (1995).

50. "Use of thermolysin metalloprotein affinity metal chromatography in the decontamination of actinide-bearing solutions." Meier, L.; Terrell, K.; Vincent, J. B. J. Chem. Techn. Biotechn. 64, 149-52 (1995).

51. "An Unsymmetric Trinuclear Chromium(III) Oxo Carboxylate Assembly: Structure and Characterization of Cr3O(O2CPh)4(8-hqn)3·1.25CH2Cl2." Nagi, M. K.; Harton, A.; Donald, S.; Lee, Y.-S.; Sabat, M.; O'Connor, C. J.; Vincent, J. B. Inorg. Chem. 34, 3813-20 (1995).

52. "Transferrin metalloprotein affinity metal chromatography." Spires, K.; Vincent, J. B. J. Chem. Techn. Biotechn. 62, 373-9 (1995).

53. "A Biologically Active Form of Chromium May Activate a Membrane Phosphotyrosine Phosphatase (PTP)." Davis, C. M.; Sumrall, K. H.; Vincent, J. B. Biochemistry 35, 12963-12969 (1996).

54. "Immobilization of conalbumin onto polystyrene/divinylbenzene co-polymers: towards finding the best support for MAMC." Gonzalez-Vergara, E.; Vincent, J. B. J. Mol. Recogn. 9, 558-563 (1996).

55. "Silica-conalbumin conjugate as an inexpensive alternative for metalloprotein affinity metal chromatography." Gonzalez-Vergara, E.; Vincent, J. B. J. Environ. Sci. Health, Part A. A31, 2337-2347 (1996).

56. "Synthetic Multinuclear Chromium Assembly Activates Insulin Receptor Kinase Activity: Functional Model for Low-Molecular-Weight Chromium-Binding Substance." Davis, C. M.; Royer, A. C.; Vincent, J. B. Inorg. Chem. 36, 5316-5320 (1997).

57. "Chromium in carbohydrate and lipid metabolism." Davis, C. M.; Vincent, J. B. J. Biol. Inorg. Chem. 2, 675-679 (1997).

58. "Chromium Oligopeptide Activates Insulin Receptor Tyrosine Kinase Activity." Davis, C. M.; Vincent, J. B. Biochemistry 36, 4382-4385 (1997).

59. "Isolation and characterization of a biologically active chromium oligopeptide from bovine liver." Davis, C. M.; Vincent, J. B. Arch. Biochem. Biophys. 339, 335-343 (1997).

60. "Synthesis and Characterization of Novel Oxo-Bridged Dinuclear and Hydroxo-Bridged Trinuclear Chromium(III) Assemblies." Harton, A.; Terrell, K.; Huffman, J. C.; MacDonald, C.; Beatty, A.; Li, S.; O'Connor, C. J.; Vincent, J. B. Inorg. Chem. 36, 4875-4882 (1997).

61. "Detection of structural changes upon oxidation in multinuclear Mn-oxo-carboxylate assemblies by Fourier transform infrared spectroscopy: relationship to photosystem II." Smith, J. C.; Gonzalez-Vergara, E.; Vincent, J. B. Inorg. Chim. Acta 255, 99-103 (1997).

62. "Copper binding and release by immobilized transferrin: a new approach to heavy metal removal and recovery." Spears, D. R.; Vincent, J. B. Biotechnol. Bioeng. 53, 1-9 (1997).

63. "Is glucose tolerance factor an artifact produced by acid hydrolysis of low-molecular-weight chromium-binding substance?" Sumrall, K. H.; Vincent, J. B. Polyhedron 16, 4171-4177 (1997).

64. "The use of dialysis cassettes in metalloprotein affinity metal chromatography (MAMC) and the stability of immobilized transferrin." Sun, Y.; Cosper, N.; Vincent, J. B. Int. J. Bio-Chromatogr. 2, 283-292 (1997).

65. "Concealed Asymmetry in an Exchange-Coupled Trichromium(III) Cluster: Structure and Magnetic Spectrum of [Cr3O(OOCPh)6(py)3](py)·0.5ClO4." Cannon, R. D.; Jayasooriya, U. A.; Sowrey, F. E.; Tilford, C.; Little, A.; Bourke, J. P.; Rogers, R. D.; Vincent, J. B.; Kearley, G. J. Inorg. Chem. 37, 5675-5677 (1998).

66. "Nuclear magnetic resonance studies of chromium(III) pyridinecarboxylate complexes." Kingry, K. F.; Royer, A. C.; Vincent, J. B. J. Inorg. Biochem. 72, 79-88 (1998).

67. "DNA nicking by a trinuclear chromium complex." Parand, A.; Royer, A. C.; Cantrell, T. L.; Weitzel, M.; Memon, N.; Vincent, J. B.; Crowder, M. W. Inorg. Chim. Acta 268, 211-219 (1998).

68. "Metalloprotein affinity metal chromatography." Vincent, J. B.; Woski, S. A. Recent Res. Dev. Biotechnol Bioeng. 1, 1-17 (1998).

69. "New tetranuclear metal carboxylate clusters with the [M4(μ3-O)2]8+ (M = MnIII or FeIII) cores: crystal structures and properties of [Mn4O2Cl2(O2CC6H3F2-3,5)6(py)4], [Fe4O2Cl2(O2CMe)6(bpy)2] and [NBu4][Fe4O2(O2CMe)7(pic)2]." Wemple, M. W.; Coggin, D. K.; Vincent, J. B.; McCusker, J. K.; Strieb, W. E.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Chem. Soc., Dalton Trans., 719-725 (1998).

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