Green (or Greener) Industrial Applications
of Ionic Liquids
Sponsored by the
ACS
Division of Industrial & Engineering Chemistry
Green Chemistry & Engineering Subdivision
Separation Science & Technology Subdivision
Green Chemistry Institute
221st American Chemical
Society National Meeting
April 1-5, 2001, San Diego, CA
SUNDAY MORNING April 1, 2001
I. Green (or Greener) Industrial
Applications of Ionic Liquids
Ionic Liquids in Context
R. D. Rogers and K. R. Seddon, Organizer
R. D. Rogers, Presiding
8:00 — 1. Green chemistry and ionic liquids: Synergies and ironies. R. D.
Rogers
8:45 — 2. Green syntheses in ionic liquids. K. R. Seddon, M. J.
Earle
9:30 — Intermission.
9:45 — 3. Neoteric solvents: A comparative analysis of their industrial
potential. C. J. Adams
10:15 — 4. Ionic liquids as green solvents. W. M. Nelson
10:45 — 5. Comparison of the behavior of ionic liquids with supported
reagents. R. M. Pagni, G. W. Kabalka
11:15 — Discussion.
SUNDAY AFTERNOON April 1, 2001
II. Green (or Greener) Industrial
Applications of Ionic Liquids
Separations and Engineering
R. D. Rogers and K. R. Seddon, Organizer
P. Wasserscheid, Presiding
1:30 — 30. Liquid-liquid equilibria in ionic liquid-organic solvent systems. K.
N. Marsh, A. Deev, L. R. Weatherley, A. C. Wu
2:15 — 31. Characterization of solute solvent properties in ionic
liquids by gas chromatography. W. M. Reichert, A. E. Visser, R. P.
Swatloski, R. D. Rogers, M. Koel
2:45 — 32. Electrochemical behavior of actinide compounds
electrochemically generated in ionic liquid media. W. R. Pitner, D.
Sanders, A. E. Bradley, K. R. Seddon, R. C. Thied, J. E. Kingston, H. E. Simms
3:15 — Intermission.
3:30 — 33. Ionic liquids as novel diluents for solvent extraction of
metal salts by crown ethers. R. A. Bartsch, S. Chun, S. V. Dzyuba
4:00 — 34. Supported ionic liquid membrane reactors: Energy savings with
reduced materials requirements. R. T. Carlin, J. Fuller
4:30 — 35. Supported ionic liquid membranes and facilitated ionic liquid
membranes. P. Scovazzo, A. E. Visser, J. H. Davis Jr., R. D. Rogers, R.
D. Noble, C. Koval
5:00 — Discussion.
MONDAY MORNING April 2, 2001
III. Green (or Greener) Industrial
Applications of Ionic Liquids
Green Synthesis
R. D. Rogers and K. R. Seddon, Organizer
J. H. Davis Jr., Presiding
8:00 — 165. Clean Synthesis in Ionic Liquids. M. J. Earle
8:45 — 166. Ionic liquids: Novel solvents for synthesis of advanced
materials. S. Dai, C. E. Barnes
9:15 — 167. Free radical polymerization and copolymerization in room
temperature ionic liquids. L. Bu, M. Li, H. Zhang, K. Hong, J. W. Mays
9:45 — Intermission.
10:00 — 168. Controlled radical polymerization in ionic liquids. D. M.
Haddleton, A. J. Carmichael, D. A. Leigh
10:30 — 169. Effectiveness of room temperature ionic liquids as solvents
for free radical addition polymerization. M. G. Benton, C. S. Brazel
11:00 — 170. Green synthesis: Aromatic nitration in ionic liquids. S.
T. Handy, C. Egrie
11:30 — 171. Aluminum catalyzed Diels-Alder reactions in ambient
temperature ionic liquids. T. B. Gunnoe, B. Arrowod, M. Travis
12:00 — Discussion.
MONDAY AFTERNOON April 2, 2001
IV. Green (or Greener) Industrial
Applications of Ionic Liquids
Nuclear and Electrochemistry
R. D. Rogers and K. R. Seddon, Organizer
W. Tumas, Presiding
1:30 — 228. Studies of the radiation stability of ionic liquids. R. C. Thied,
A. Haile, B. Lewin, W. R. Pitner, A. E. Bradley, D. Sanders, D. Rooney, K. R.
Seddon, H. E. Sims, G. Baston, G. W. A. Newton, M. J. F. Healy, I. Hamblett, D.
Allen, B. Hodgson, T. Gorman
2:15 — 229. Superoxide electrochemistry in ionic liquids. M. L. Leonard,
M. C. Kittle, M. A. Matthews, J. W. Weidner
2:45 — 230. Applications of room temperature ionic liquids: Actinide
separations. R. D. Rogers, A. E. Visser, R. P. Swatloski, S. T. Griffin,
W. M. Reichert
3:15 — Intermission.
3:30 — 231. Actinide chemistry in room temperature ionic liquids. W.
J. Oldham Jr., D. A. Costa, B. L. Scott, W. H. Smith, K. D. Abney
4:00 — 232. Ionic liquids: From green chemistry to ore refining. A.
McCluskey, G. A. Lawrance, M. Owen, I. C. Hamilton
4:30 — 233. Liquid ionic phosphates (LIPS): Electrochemical and
spectroscopic properties. S. I. Lall, D. Mancheno, R. Casiano, J. I.
Cohen, R. Engel
5:00 — 234. Potential applications of ionic liquids in aluminum
industries. B. Wu, R. G. Reddy, R. D. Rogers
5:30 — Discussion.
TUESDAY MORNING April 3, 2001
V. Green (or Greener) Industrial
Applications of Ionic Liquids
Ionic Liquid Systems
R. D. Rogers and K. R. Seddon, Organizer
J. F. Brennecke, Presiding
8:00 — 245. Ionic liquids in perspective: The past with an eye toward the
industrial future. J. S. Wilkes
8:45 — 246. Highly acidic, non-chloroaluminate ionic liquids P.
Wasserscheid, M. Sesing
9:15 — 247. New ionic liquids: Alkyl-substituted pyrylium salts and
their conversion into pyridinium salts. A. T. Balaban, M. J. Lesko, W.
A. Seitz
9:45 — Intermission.
10:00 — 248. Liquid ionic phosphates (LIPs): Syntheses and
purifications. J. I. Cohen, S. I. Lall, D. Mancheno, S. Castro, R. Engel
10:30 — 249. Significance of cations in ionic liquids chemistry. K.
E. Johnson, L. Xiao, G. Driver
11:00 — 250. Working Salts: Syntheses and uses of ionic liquids
containing functionalized ions. J. H. Davis Jr.
11:30 — Discussion.
TUESDAY AFTERNOON April 3, 2001
VI. Green (or Greener) Industrial
Applications of Ionic Liquids
Properties of Ionic Liquids
K. R. Seddon, Organizer
R. D. Rogers, Organizer, Presiding
1:30 — 279. Gas solubility in ionic liquids. J. L. Anthony, Z. Gu, L. A.
Blanchard, E. J. Maginn, J. F. Brennecke
2:15 — 280. Influence of chloride, water, and organic solvents on the
physical properties of ionic liquids B. J. McAuley, K. R. Seddon, A.
Stark, M. Torres
2:45 — 281. Free energy relationships and solvatochromic properties of
room temperature ionic liquids based on methylimmidazolium cations. J. G.
Huddleston, G. A. Broker, H. D. Willauer, A. E. Visser, W. M. Reichert, R.
D. Rogers
3:15 — Intermission.
3:30 — 282. Viscosity and density of 1-alkyl-3-methylimidazolium ionic
lquids. N. A. Hamill, K. R. Seddon, A. Stark, M. Torres
4:00 — 283. Solution thermodynamics of imidazolium-based ionic liquids
and water. J. L. Anthony, E. J. Maginn, J. F. Brennecke
4:30 — 284. Research opportunities derived from the Molten Salt Database
project. M. Gaune-Escard, J. Fuller
5:00 — 285. Intellectual property rights with special reference to ionic
liquids. O. J. Safriel, A. B. McEwen, V. R. Koch
WEDNESDAY MORNING April 4, 2001
VII. Green (or Greener) Industrial
Applications of Ionic Liquids
Catalysis I
R. D. Rogers, Organizer
K. R. Seddon, Organizer, Presiding
8:00 — 308. Biphasic catalysis using supercritical carbon dioxide and ionic
liquids. W. Tumas, F. Liu, R. T. Baker
8:45 — 309. Ionic liquids-polar, weakly coordinating solvents for the
biphasic oligomerization of ethylene to a-olefins with cationic Ni-complexes W.
Keim, P. Wasserscheid, C. Hilgers
9:15 — 310. Palladium catalyzed coupling reactions in room-temperature
ionic liquids. T. Welton, P. J. Smith, C. J. Mathews
9:45 — Intermission.
10:00 — 311. Catalytic oxidations in ionic liquids. M. M. Abu-Omar
10:30 — 312. Palladium-catalyzed carbonylation of aryl halides in ionic
liquids. T. Hayashi, E. Mizushima, M. Tanaka
11:00 — 313. Transition metal catalyzed hydrosilylation and
hydroboration of acetylenes in ionic liquids. M. Vaultier
11:30 — Discussion.
WEDNESDAY AFTERNOON April 4, 2001
VIII. Green (or Greener) Industrial
Applications of Ionic Liquids
Catalysis II
R. D. Rogers and K. R. Seddon, Organizer
C. J. Adams, Presiding
1:30 — 340. Bioprocess applications of ionic liquids: Opportunities and
challenges. G. J. Lye
2:15 — 341. Reactivity of lignocellulosic biomass derivatives in ionic
liquids. L. Moens, N. Khan
2:45 — 342. Green chemistry, the carbohydrate economy, and ionic
liquids: Compatible goals, compatible chemistries? R. D. Rogers, M. A.
Godshall, T. P. Johnson, L. Moens, S. K. Spear
3:15 — Intermission.
3:30 — 343. Biphasic hydroformylation of 1-octene using ionic liquids as
catalyst phase. P. Wasserscheid, H. Waffenschmidt, C. C. Brasse, A.
Salzer, P. Machnitzki, O. Stelzer
4:00 — 344. Chymotrypsin-catalyzed transesterification in ionic liquids
and ionic liquid/supercritical carbon dioxide. J. A. Laszlo, D. L.
Compton
4:30 — 345. Green synthesis: Ionic liquids and cross coupling reactions.
S. T. Handy, X. Zhang, S. Sternberger
5:00 — Discussion
THURSDAY MORNING April 5, 2001
IX. Green (or Greener) Industrial
Applications of Ionic Liquids
Structure and Photochemistry
R. D. Rogers and K. R. Seddon, Organizer
R. M. Pagni, Presiding
8:00 — 370. Structural studies of imidazolium based ionic liquids. C. Hardacre,
J. D. Holbrey, S. E. J. McMath, M. Nieuwenhuyzen, C. Hanke
8:45 — 371. Designing structure in ionic liquids: A consideration of
shape, charge density, and composition J. D. Martin
9:15 — 372. Imidazolium melts with carborane anions: Why are ionic
liquids liquid? C. A. Reed, A. S. Larsen
9:45 — Intermission.
10:00 — 373. 1-Alkyl-3-methylimidazolium tetrachloropalladate(II) and
platinate((II) salts, the structure of ionic liquid catalysts J. D. Holbrey,
S. Johnston, M. Nieuwenhuyzen, K. R. Seddon
10:30 — 374. Photochemical and photophysical investigations in ionic
liquids. C. M. Gordon, M. J. Muldoon, I. R. Dunkin, A. J. McLean
11:00 — 375. Fluorescence quenching of polycyclic aromatic hydrocarbons
within room-temperature ionic liquids. S. Pandey, K. A. Fletcher, A. E.
Hendricks
11:30 — Discussion.
THURSDAY AFTERNOON April 5, 2001
X. Green (or Greener) Industrial
Applications of Ionic Liquids
High Temperature and Other Systems
R. D. Rogers and K. R. Seddon, Organizer
L. Moens, Presiding
1:30 — 405. Catalytic and electrochemical processes for SO2 and NOx
emission abatement: Part I. S. Boghosian, B. S. Bal'zhinimaev, M.
Eriksen, R. Fehrmann, V. Parvulescu, J. Winnick, A. Zagoruiko, Y. N. Zhukov
2:00 — 406. Catalytic and electrochemical processes for SO2
and NOx emission abatement: Part II. R. Fehrmann, B. S.
Bal'zhinimaev, S. Boghosian, M. Eriksen, V. Parvulescu, J. Winnick, A.
Zagoruiko, Y. N. Zhukov
2:30 — 407. Ionic liquids as benign solvents for extraction of
astaxanthin and solubilization of chitin. S. K. Spear, W. M. Reichert,
R. P. Swatloski, R. D. Rogers
3:00 — Intermission.
3:15 — 408. Ammonolysis in supercritical ammonia. W. S. Anderson,
H. J. Hyer, T. P. Rudy, J. E. Sundberg
3:45 — 409. Low temperature acetamide-based melts for electrochemical
processes. O. Boiko, S. Kochetova, A. Furman, N. Tumanova
4:15 — 410. Electrodeposition of oxygen-free tantalum and synthesis of
novel oxygen-containing tantalum compounds from molten salts. V. V.
Grinevitch, A. V. Arakcheeva, L. P. Polyakova, E. G. Polyakov
4:45 — 411. Synthesis of phosphorous compounds in ionic liquids. N.
P. Tarasova, Y. V. Smetannikov, D. E. Polyansky, O. B.
Lapina
5:15 — Discussion.
SUNDAY EVENING April 1, 2001 (I&EC POSTER SESSION)
MONDAY EVENING April 2, 2001 (SCI-MIX)
General Poster Session
Green (or Greener) Applications of Ionic Liquids
R. D. Rogers and K. R. Seddon, Organizer
A. H. Bond, Organizer, Presiding
8:00 - 10:00 pm
48.
Potential application of ionic liquids for olefin oligomerization. A.
Ranwell, M. Tshamano
49. Comparative study of the chemical and physical properties of
hydrophobic versus hydrophilic ionic liquids. R. D. Rogers, A. E. Visser,
W. M. Reichert, R. P. Swatloski
50. Characteristics of room temperature ionic liquids in various
water/ethanol solutions. R. P. Swatloski, A. E. Visser, W. M. Reichert,
R. D. Rogers
51. Free energy relationships and solvatochromic properties of aqueous
solvent systems based on poly(ethylene) glycol. J. G. Huddleston, H. D.
Willauer, R. D. Rogers
52. Solubilization and derivatization of chitin in room temperature
ionic liquids. W. M. Reichert, A. E. Visser, R. P. Swatloski, S. K.
Spear, R. D. Rogers
53. Solubility of mono- and di-saccharides in ionic liquids. S. K.
Spear, G. A. Broker, M. A. Klingshirn, L. Moens, M. A. Godshall, T. P.
Johnson, R. D. Rogers
54. Supported ionic liquid membranes and facilitated ionic liquid
membranes. P. Scovazzo, A. E. Visser, J. H. Davis Jr., R. D. Rogers, C.
Koval, R. D. Noble
55. Ionic liquids: Clean solvents for organic synthesis. C. M. Gordon,
C. A. Ohlin, C. Ritchie
56. Gas solubility and the effect on reactions in ionic liquids. D.
W. Rooney, C. Hardacre, S. Kadare
57. Photoinduced energy transfer and hydrogen abstraction reactions in
ionic liquids. M. J. Muldoon, C. M. Gordon, A. J. McLean, I. R. Dunkin
58. Electrochemical and EXAFS investigations of uranium compounds in
ionic liquids. W. R. Pitner, A. E. Bradley, D. Sanders, K. R. Seddon, M.
Nieuwenhuyzen, R. C. Thied, J. E. Kingston
59. Plutonium chemistry in room temperature ionic liquids. D. A.
Costa, W. H. Smith, W. J. Oldham
60. Electrochemical and spectroscopic characteristics of polycationic
liquid ionic phosphates. S. I. Lall, D. Mancheno, R. Casiano, J. I.
Cohen, R. Engel
61. Highly acidic ionic liquids for carbonylation of aromatic compounds.
P. S. van Heerden, P. Wasserscheid, A. Willemse
62. Polycationic NAILs: Isolation of two types from hexafluorophosphoric
acid reaction with polycationic halides. J. I. Cohen, S. Castro, V.
Behaj, D. Mancheno, S. I. Lall, R. Engel
63. Polycationic salts: New anions with "strings" and
"rings". S. Castro, V. Behaj, A. Rikin, S. I. Lall, J. I.
Cohen, R. Engel
64. Organostannanes and ionic liquids: Toward green chemistry. A.
McCluskey, D. J. Young
65. Structure-property relationships in hexafluorophosphate-containing
room-temperature ionic liquids. S. V. Dzyuba, R. A. Bartsch