ROOM TEMPERATURE IONIC LIQUIDS AS ALTERNATIVES TO ORGANIC SOLVENTS IN LIQUID/LIQUID EXTRACTION

7/10/99


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Table of Contents

ROOM TEMPERATURE IONIC LIQUIDS AS ALTERNATIVES TO ORGANIC SOLVENTS IN LIQUID/LIQUID EXTRACTION

Why Consider Ionic Liquids?

Room Temperature Ionic Liquids

Important IL Properties

Characteristics of RTIL

Typical IL Cations

Anions for RTIL

Chloroaluminate Ionic Liquids

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Low Melting 1-decyl-3-methylimidazolium [PF6]

Effect of the Anion on Melting Points of [emim]+ IL

Effect of the Cation on Melting Points of [triflate]- IL

Effect of Alkyl Chain Length on IL Viscosity and Density

Effect of Anion on IL Mechanical Properties

Applications as Solvents

Recent Activity with RTIL as Solvents

Catalysis

IL in Two-Phase Catalytic Hydrogenation Reactions

Applications in Synthesis

Electrochemistry

Separations

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Sources of Ionic Liquids

Future IL Research Needs

Further Information Regarding Physical Properties, Chemistry, and Uses of Ionic Liquids

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The University of Alabama Center for Green Manufacturing

Rogers Group Personnel

Author: Robin D. Rogers

Email: RDRogers@bama.ua.edu

Home Page: http://bama.ch.ua.edu/~rdrogers

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