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Refereed Publications

  1. Huddleston, J. G.; Willauer, H. W.; Swatloski, R. P.; Visser, A. E.; Rogers, R. D. "Room Temperature Ionic Liquids as Novel Media for 'Clean' Liquid-Liquid Extraction," Chem. Commun. 1998, 1765-1766.

  2. Sharma, C. V. K.; Swatloski, R. P.; Rogers, R. D. "4,4'-Dipyridine•2H 2O: Complementarity of Hydrogen Bond Donor:Acceptor Ratio," Crystal Eng. (Suppl., Mat. Res. Bull.) 1998, 1, 153-158.

  3. Rogers, R. D.; Visser, A. E.; Swatloski, R. P.; Hartman, D. H. "Metal Ion Separations in Room Temperature Ionic Liquids: Potential Replacements for Volatile Organic Diluents," In Metal Separation Technologies Beyond 2000: Integrating Novel Chemistry with Processing; Liddell, K. C.; Chaiko, D. J., Eds.; The Minerals, Metals & Materials Society: Warrendale, PA, 1999; pp 139-147.

  4. Visser, A. E.; Swatloski, R. P.; Hartman, D. H.; Huddleston, J. G.; Rogers, R. D. "Calixarenes as Ligands in Environmentally-Benign Liquid/Liquid Extraction Media, Aqueous Biphasic Systems and Room Temperature Ionic Liquids," In Calixarenes for Separations; Lumetta, G. J.; Rogers, R. D.; Gopalan, A. S., Eds.; ACS Symposium Series 757, American Chemical Society: Washington, DC, 2000, 223-236.

  5. Visser, A. E.; Swatloski, R. P.; Reichert, W. M.; Griffin, S. T.; Rogers, R. D. “Traditional Extractants in Nontraditional Solvents: Groups 1 and 2 Extraction by Crown Ethers in Room-Temperature Ionic Liquids,” Ind. Eng. Chem. Res. 2000, 39, 3596-3604.

  6. Visser, A. E.; Swatloski, R. P.; Rogers, R. D. "pH-Dependent Partitioning in Room Temperature Ionic Liquids Provides a Link to Traditional Solvent Extraction Behavior," Green Chemistry 2000, 2, 1-4.

  7. Spear, S. K.; Visser, A. E.; Willauer, H. W.; Swatloski, R. P.; Griffin, S. T.; Huddleston, J. G.; Rogers, R. D. "Green Separations Science & Technology: Replacement of Volatile Organic Compounds in Industrial Scale Liquid-Liquid or Chromatographic Separations," In Green Engineering; Anastas, P. T.; Heine, L. G.; Williamson, T. C., Eds.; ACS Symposium Series 766, American Chemical Society: Washington, DC, 2001; pp 206-221.

  8. Rogers, R. D.; Spear, S. K.; Swatloski, R. P.; Reichert, W. M.; Godshall, M. A.; Johnson, T. P.; Moens, L.; “Non-sugar products from sugarcane for the new millennium: green pathways to a carbohydrate-economy?” Publ. Tech. Pap. Proc. Annu. Meet. Sugar Ind. Technol. 2001, 60 291-301.

  9. Spear, S. K.; Visser, A. V.; Willauer, H. D.; Swatloski, R. P.; Griffin, S. T.; Huddleston, J. G.; Rogers, R. D.; “Green separation science and technology: replacement of volatile organic compounds in industrial scale liquid-liquid or chromatographic separations,” ACS Symp. Ser. 2001, 766 (Green Engineering), 206-221.

  10. Visser, A. E.; Swatloski, R. P.; Hartman, D. H.; Huddleston, J. G.; Rogers, R. D.; “Calixarenes as Ligands in Environmentally-Benign Liquid-Liquid Extraction Media, Aquous Biphasic Systems and Room Temperature Ionic Liquids,” ACS Symp. Ser., 2000, 757 (Calixarenes for Separations), 223-236.

  11. Visser, A. E.; Reichert, W. M.; Swatloski, R. P.; Willauer, H. D.; Huddleston, J. G.; Rogers, R. D. “Characterization of Hydrophilic and Hydrophobic Ionic Liquids: Alternatives to Volatile Organic Compounds for Liquid-liquid Separations,” In Green Industrial Applications of Ionic Liquids, Rogers, R. D. and Seddon, K. R. (Eds.); American Chemical Society: Washington DC, 2002, 818 289-308.

  12. Visser, A. E.; Swatloski, R. P.; Griffin, S. T.; Hartman, D. H.; Rogers, R. D. "Liquid/Liquid Extraction of Metal Ions in Room Temperature Ionic Liquids," Sep. Sci. Technol. 2001 , 36, 785-804.

  13. Visser, A. E.; Swatloski, R. P.; Reichert, W. M.; Mayton, R.; Sheff, S.; Wierzbicki, A.; Davis, Jr. J. H.; Rogers, R. D. “Task-Specific Ionic Liquids for the Extraction of Metal Ions from Aqueous Solutions,” Chem. Commun. 2001, 135-136.

  14. Swatloski, R. P.; Visser, A. E.; Reichert, W. M.; Broker, G. A.; Farina, L. M.; Holbrey, J. D.; Rogers, R. D. “Solvation of 1-butyl-3-methylimidazolium hexafluorophosphate in aqueous ethanol—a green solution for dissolving ‘hydrophobic’ ionic liquids,” Chem. Commun. 2001, 20, 2070-2071.

  15. Swatloski, R. P.; Visser, A. E.; Reichert, W. M.; Broker, G. A.; Farina, L. M.; Holbrey, J. D.; Rogers, R. D. “On the solubilization of water with ethanol in hydrophobic hexafluorophosphate ionic liquid,” Green Chemistry 2002, 81-87.

  16. Visser, A. E.; Swatloski, R. P.; Reichert, W. M.; Willauer, H. D.; Huddleston, J. G.; Rogers, R. D. “Room temperature ionic liquids as replacements for traditional organic solvents and their applications towards ‘green chemistry’ in separation processes,” NATO Sci. Ser. IV, 2002, Vol. 18 (Green Industrial Applications of Ionic Liquids), 137-156.

  17. Swatloski, R. P.; Spear, S. K.; Holbrey, J. D.; Roger, R. D. “Dissolution of Cellose with Ionic Liquids,” J. Am. Chem. Soc. 2002, 124, 4974-4975.

  18. Visser, A. E.; Swatloski, R. P.; Reichert, W. M.; Mayton, R.; Sheff, S.; Wierzbicki, R.; Davis, J. H. Jr.; Rogers, R. D.; “Task-Specific Ionic Liquids Incorporating Novel Cations for the Coordination and Extraction of Hg 2+ and Cd 2+: Synthesis, Characterization, and Extraction Studies,” Environmental Science and Technology, 2002, 36, 2523-2529.

  19. Swatloski, R. P.; Holbrey, J. D.; Spear, S. K.; Rogers, R. D. “Ionic Liquids for the dissolution and regeneration of cellulose,” in Molten Salts XIII, Proceedings of the thirteenth international symposium on molten salts, Eds H. C. De Long, R. W. Bradshaw, M. Matsunaga, G. R. Stafford, P. C. Truelove, 2002, 155-165.

  20. Holbrey, J. D.; Reichert, W. M.; Swatloski, R. P.; Broker, G. A.; Pitner, W. R.; Seddon, K. R.; Rogers, R. D. “Efficient, halide-free synthesis of new, low cost ionic liquids: 1,3-dialkylimidozolium salts containing methyl- and ethylsulfate anions,” Green Chemistry 2002, 4, 407-413.

  21. Holbrey, J. D.; Visser, A. E.; Spear, S. K.; Reichert, W. M.; Swatloski, R. P.; Broker, G. A.; Rogers, R. D. “Mercury(II) partitioning from aqueous solutions with a new, hydrophilic ethylene-glycol functionalized bis(methylimidazolium) ionic liquid,” Green Chem., 2003, 5, 129-135.

  22. Gutowski, K. E.; Broker, G. A.; Willauer, H. D.; Huddleston, J. G.; Swatloski, R. P.; Holbrey, J. D.; Rogers, R. D. “Controlling the aqueous miscibility of ionic liquids: Aqueous biphasic systems of water-miscible ionic liquids and water-structuring salts for recycle, metathesis, and separations,” J. Am. Chem. Soc., 2003, 125, 6632-6633.

  23. Swatloski, R. P.; Holbrey, J. D.; Rogers, R. D. “Ionic liquids are not always green: hydrolysis of 1-butyl-3-methylimidazolium hexafluorophosphate,” Green Chem., 2003, 5, 361-363.

  24. Visser, A. E.; Swatloski, R. P.; Reichert, W. M.; Willauer, H. D.; Huddleston, J. G.; Rogers, R. D. Room temperature ionic liquids as replacements for traditional organic solvents and their applications towards ‘green chemistry’ in separation processes. In Green Industrial Applications of ionic Liquids; Rogers, R. D.; Seddon, K. R.; Volkov, S., Eds.; NATO Science Series, II: Mathematics, Physics and Chemistry92, Kluwer Academic Publishers: Dordrecht , 2003; pp. 137-156.

  25. Gutowski, K. E.; Bridges, N. J.; Cocalia, V. A.; Spear, S. K.; Holbrey, J. D.; Swatloski, R. P.; Davis, J. H., Jr.; Rogers, R. D. “Approaches to Nuclear Separations Using Room Temperature Ionic Liquids,” American Nuclear Society GLOBAL 2003 Winter Meeting Proceedings 2003; pp 1604-1608.

  26. Chen, J.; Spear, S. K.; Huddleston, J. G.; Holbrey, J. D.; Swatloski, R. P.; Rogers, R. D. “Application of Poly(ethylene glycol)-based Aqueous Biphasic Systems as Reaction and Reactive Extraction Media,” Ind. Eng. Chem. Res., 2004, 43, 5358 – 5364.

  27. Swatloski, R. P.; Holbrey, J. D.; Memon, S. B.; Caldwell, G. A.; Caldwell, K. A.; Rogers, R. D. “ Using Caenorhabditis elegans to probe toxicity of 1-alkyl-3-methylimidazolium chloride based ionic liquids,” Chem Commun., 2004, 668-669.

  28. Wang, W.; Shen, G.; Swatloski, R. P.; Farag, R.; Broughton, Jr., R. M.; Rogers, R. D. “Cellulose Fibers Extruded from Ionic Liquids,” In Proceedings of the International Nonwovens Technical Conference, Toronto Canada, September 20-23, 2004, INDA, Association of the Nonwoven Fabrics Industry: Cary, NC, 2004.

  29. Moulthrop, J. S.; Swatloski, R. P.; Moyna, G.; Rogers, R. D. “ High-resolution 13C NMR studies of cellulose and cellulose oligomers in ionic liquid solutions,” Chem. Commun. 2005, 1557-1559.

  30. Haque, A.; Daly, D. T.; Rogers, R. D.; Mobley, C.; Swatloski, R. P. “Effects of MAPP as Coupling Agent on the Performance of Cellulose/Polypropylene Laminated Composites,” In Proceedings of the 3 rd International Conference on Eco-Composites, Royal Institute of Technology, Stockholm, Sweden, June 20-21, 2005.

  31. Holbrey, J. D.; Chen, J.; Turner, M. B.; Swatloski, R. P.; Spear, S. K.; Rogers, R. D., “Applying Ionic Liquids for Controlled Processing of Polymer Materials,” In Ionic Liquids in Polymer Systems: Solvents, Additives, and Novel Applications, Brazel, C. S.; Rogers, R. D. (Eds.); ACS Symposium Series 913; American Chemical Society: Washington DC, 2005; pp 71-87.

  32. Wang, W.; Shen, G.; Swatloski, R. P.; Farag, R.; Broughton, Jr., R. M.; Rogers, R. D. “A New Solvent for Cellulose Extrusion,” In Proceedings of the Cotton Beltwide Conferences, New Orleans, LA, January 4-8, 2005, National Cotton Council: Memphis, TN, 2005.

  33. Fort, D. A.; Swatloski, R. P.; Moyna, P.; Rogers, R. D.; Moyna, G. “Use of Ionic Liquids in the Study of Fruit Ripening by High-Resolution 13C NMR Spectroscopy: ‘Green’ Solvents Meet Green Bananas,” Chem Commun. 2006, 714-716. (Highlighted as a Hot Article by Chem. Commun. January 16, 2006, URL: http://www.rsc.org/Publishing/Journals/cc/index.asp; last accessed January 19, 2006; Highlighted in Ritter, S. “Ionic liquids go bananas,” Chemical & Engineering News, February 6, 2006, p. 48; Listed as a ‘Top Ten’ accessed article by Chem. Commun. for the month of January 2006 at http://www.rsc.org/chemcomm; Highlighted in Lavender, R. “Following the ripening of bananas,” Chemical Science (an RSC web supplement) February 23, 2006 at URL: http://www.rsc.org/Publishing/ChemScience/Volume/2006/03/ripening_of_bananas.asp; last accessed April 17, 2006.)

  34. Remsing, R. C.; Swatloski, R. P.; Rogers, R. D.; Moyna, G. “Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems,” Chem. Commun. 2006, 1271-1273.

  35. Swatloski, R. P.; Holbrey, J. D.; Weston, J. L.; Rogers, R. D. “ Preparation of magnetic cellulosic composites using ionic liquids,” Chimica Oggi 2006, 24, 31-3.

  36. Fort, D. A.; Remsing, R. C.; Swatloski, R. P.; Moyna, P.; Moyna, G.; Rogers, R. D. “Can ionic liquids dissolve wood? Processing and analysis of lignocellulosic materials with 1-n-butyl-3-methylimidazolium chloride,” Green Chem., 2007, 1, 63-69.

  37. Smiglak, M.; Holbrey, J. D.; Griffin, S. T.; Reichert, W. M.; Swatloski, R.P.; Katritzky, A. R.; Yang, H.; Zhang, D.; Kirichenko, K.; Rogers, R. D.  "Ionic Liquids via reaction of the zwitterionic 1,3-dimethylimidazolium-2-carboxylate with protic acids. Overcoming synthetic limitations and establishing new halide free protocols for the formation of ILs," Green Chem. 2007, 9, 90-98.

  38. Reichert, W. M.; Holbrey, J. D.; Swatloski, R. P.; Gutowski, K. E.; Visser, A. E.; Nieuwenhuyzen, M.; Seddon, K. R.; Rogers, R. D. “Solid‑state analysis of low‑melting 1,3‑dialkylimidazolium hexafluorophosphate salts (ionic liquids) by combined X‑ray crystallographic and computational analyses,” Crystal Growth and Design, submitted.

  39. Sun, N.; Swatloski, R. P.; Maxim, M. L.; Broughton, R. M.; Spear, S. K.; Daly, D. T.; Haque, A.; Harland, A. G. Rogers, R. D. “Cellulose fibres prepared from direct dissolution of cellulose in ionic liquid,” Proceed. 4th Inter. Conf. of Text. Res. Div. NRC Cairo, Egypt, April 14-17, 2007; Textile Processing: State of the Art & Future Developments, 2007, 4(2), 139 – 143.

  40. Poplin, J. H.; Swatloski, R. P.; Holbrey, J. D.; Spear, S. K.; Metlen, A.; Grätzel, M.; Nazeeruddin, M. K.; Rogers, R. D. “Sensor technologies based on a cellulose supported platform,” Chem. Comm., 2007, 2025-2027.

  41. Poplin, J. H.; Rudkevich, D. M.; Swatloski, R. P.; Rogers, R. D. “Development of ionic liquid membranes for NOx gas detection and stroage utilizing Calix[4]Arenes,“ In Molten Salts XVI: Proceedings of the International Symposium, Turlove, P. C.; DeLong, H. C.; Mantz, R. A.; Stafford, G. R.; Matsunaga, M. Eds.; The Electrochemical Society: Pennington, 2007.

  42. Hough, W. L.; Smiglak, M.; Rodríguez, H.; Swatloski, R. P.; Spear, S. K.; Daly, D. T.; Pernak, J.; Grisel, J. E.; Carliss, R. D.; Soutullo, M. D.; Davis, Jr., J. H.; Rogers, R. D. “The third evolution of ionic liquids: active pharmaceutical ingredients,” New J. Chem., 2007, 31, 1429 – 1436.

  43. Whitcomb, D. R.; Swatloski, R. P.; Rogers, R. D. “Mode of Complex Formation Between Thiones and Silver Ion Within a Photothermographic Formulation: The Crystal and Molecular Structure of Hexa-(silver-5-methyl-2-mercaptobenzimidazole THF),” Journal of Imaging Science and Technology, 2007, 51(6), 547–551.

  44. Visser, A. E.; Huddleston, J. G.; Holbrey, J. D.; Reichert, W. M. Swatloski, R. P.; Rogers, R. D. “Hydrophobic n-alkyl-N-isoquinolinium salts: ionic liquids and low melting solids,” in ACS Symposium Series  (2007),  975 (Ionic Liquids IV),  362-380.  Publisher: American Chemical Society.

  45. Sun, N.; Swatloski, R. P.; Maxim, M. L.; Rahman, M.; Harland, A. G.; Haque, A.; Spear, S. K.; Daly, D. T.; Rogers, R. D. “Magnetite-embedded cellulose fibers prepared from ionic liquid,” J. Mater. Chem., 2008, 18, 283-290.

  46. Bagheri, M.; Rodríguez, H.; Swatloski, R. P.; Spear, S. K.; Daly, D. T.; Rogers, R. D. “Ionic Liquid-Based Preparation of Cellulose—Dendrimer Films as Solid Supports for Enzyme Immobilization,” Biomacromolecules, 2008, 9, 381-387.

  47. Bailey, M .M.; Townsend, M. B.; Jernigan, P. L.; Sturdivant, J.; Hough-Troutman, W. L.; Rasco, J. F.; Swatloski, R. P.; Rogers, R. D.; Hood, R. D. “Developmental toxicity assessment of the ionic liquid 1-butyl-3-methylimidazolium chloride in CD-1 mice,” Green Chem. in preparation.

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